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                                                                                                                                                                                                                                                                                                                                蓄電池內部溫度對其性能有很大影響

                                                                                                                                                                                                                                                                                                                                2017-12-29   |  來源:煒業通科技

                                                                                                                                                                                                                                                                                                                                對鉛酸蓄電池而言,內部溫度對其性能有很大影響,因為在充放電過程中其內部存在“氧循環”,產生的額外熱量會使溫度上升,因而影響更大,因此在判斷蓄電池的性能時,要充分考慮溫度的影響。當溫度上升時,電解液的運動速度增大,獲得動能增加,因此滲透力加強,電解液電阻減小,電化學反應增強,這些都使蓄電池容量增大。當溫度降低時,電解液的粘度增大,使離子運動受到較大阻力,擴散能力降低,滲入極板內部困難,活性物質深處由于酸的缺乏而得不到充分利用,導致容量下降。其次是電解液電阻隨溫度下降而增加,結果電池內阻增加,電壓降增大,從而容量下降。溫度變化1℃時蓄電池容量的變化量稱為容量的溫度系數。在一般情況下,容量與溫度的關系如下式所示其中Ct1為溫度在t1℃時的容量(A·h),Ct2為溫度在t2℃時的容量(A·h),K為容量的溫度系數,t1、t2為電解液的溫度(℃)。

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